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61.
Mohan B. Ponnuchamy G. Mohan Muralikrishna Venkateswara Rao Mannava G. Srinivas Reddy 《Ceramics International》2018,44(13):15019-15023
Nanocrystalline nickel oxide (NiO) was prepared from nickel hydroxide by Spark plasma sintering (SPS) and the mechanisms involved in the densification of NiO were studied. Reverse precipitated nickel hydroxide powders were SPS processed at 400, 600 and 700?°C with 70?MPa pressure. Pure NiO with 12?nm crystallite size formed after 400?°C sintering process. However NiO grains had grown to 18 and 38?nm after 600 and 700?°C sintering respectively. NiO pellets prepared using 600 and 700?°C SPS sintering schedules had relative densities of 83% and 94% respectively. Two displacement rate regimes were observed during densification of NiO in both 600 and 700?°C sintering processes. Decomposition of nickel hydroxide and particle sliding of NiO led to first displacement rate maximum while inverse Hall-Petch based plastic deformation facilitated densification during the constant second displacement rate regime. No densification occurred during sintering holding times indicating the limited role that diffusion played during densification. 相似文献
62.
Endong Jin Jingkun Yu Tianpeng Wen Xinghui Hou Beiyue Ma Feixiong Mao 《Ceramics International》2018,44(6):6390-6394
High-density magnesia was fabricated using vacuum compaction molding, and effects of forming pressure and sintering temperature on bulk density, apparent porosity, diameter shrinkage ratio, volume shrinkage ratio, pore size distribution, cold compressive strength, and thermal shock resistance of the magnesia samples were investigated. There were two ranges of pore distribution in samples that were formed via conventional compaction molding, and these ranges were about 350–2058 nm and 6037–60527 nm. It was considered that the range of larger pores mainly influenced the densification of magnesia. Using vacuum compaction molding, large size pores were removed, and high-density magnesia (with a density greater than 3.40 g cm?3) was easily prepared when forming pressure was higher than 200 MPa and sintering temperature was higher than 1600 °C. Magnesia samples prepared via vacuum compaction molding showed better performance compared to that of samples prepared via conventional compaction molding. 相似文献
63.
Xinming Ren Beiyue Ma Gaofeng Fu Fan Qian Guoqi Liu Jingkun Yu Yawei Li 《Ceramics International》2021,47(14):19959-19969
The recycling of solid waste is a win-win solution for humans and nature. For this purpose, magnesite tailings and silicon kerf waste were employed to prepare MgO–Mg2SiO4 composite ceramics by solid-state reaction synthesis in the present work. Then, effects of sintering temperature and raw material ratio on as-prepared ceramics were systematically studied. As-prepared ceramics showed improvement in their relative density (from 47.55%–68.12% to 90.96%–95.25%) and cold compressive strength (from 7.34–118.66 MPa to 303.39–546.65 MPa) with the increase in sintering temperature from 1300 to 1600 °C. In addition, it was found that Si promoted synthesis process of Mg2SiO4 phase through transient liquid phase sintering and Fe2O3 accelerated sintering process through activation sintering. Consequently, the presence of Mg2SiO4 phase effectively improved the density and strength of MgO–Mg2SiO4 composite ceramic, while reducing its thermal conductivity. This work provides a potential reutilization strategy for magnesite tailings, and as-prepared products are expected to be applied in fields of construction, metallurgy, and chemical industry. 相似文献
64.
Víctor I. Hernández Domingo I. García-Gutiérrez Juan A. Aguilar-Garib Román J. Nava-Quintero 《Ceramics International》2021,47(1):310-319
In the current study two different batches of X7R-0603 BME-MLCCs displayed dissimilar electrical performance, despite having the same chemical composition, tape casting, and sintering conditions; with the only difference between them being the ore deposits where the raw materials were extracted from to synthesize the BaTiO3. Specifically, they presented different electrical response to highly accelerated life tests (HALT). Although the chemical analysis of each slip showed the same composition, the trace elements of the BaTiO3 sources could have acted as dopants or produced different secondary phases. A search for precipitates in the two samples was conducted by means of Scanning (SEM) and Transmission Electron Microscopy (TEM) techniques. SEM observations confirmed the presence of precipitates formed within the structure of the MLCCs exhibiting the greatest decrement in their electrical resistance results during the HALT. In order to further characterize the observed precipitates, samples were prepared by Focused Ion Beam (FIB) lift-out method, to make TEM characterization of specific precipitates feasible. TEM studies were performed on the precipitates to obtain electron diffraction patterns and complementary Energy Dispersive X-Ray Spectroscopy (EDXS) chemical analysis. Based on the crystal and chemical data obtained, it can be concluded that the precipitates are a hexagonal anhydrous silicate oxyapatite phase with a stoichiometry of Ca3Y16Si10O13, and lattice parameters of a = 0.9353 nm and c = 0.6970 nm; this phase was not found in the JCPDS data base. Differences in raw materials coming from different ore deposits can produce undesired precipitates that affect the electrical performance of MLCCs. 相似文献
65.
66.
《Advanced Powder Technology》2022,33(12):103837
Direct reduction (DR) of iron ore with hydrogen is a potential route for near-zero CO2 steelmaking, but vertical shaft DR reactors require that iron ore fines must first be pelletized. This study reports an investigation of the pelletization and subsequent sintering behaviour of titanomagnetite (TTM) ironsand, which is the main iron ore feedstock for New Zealand’s steel industry. Initially green pellets were bound with bentonite and carboxymethyl-cellulose (Peridur), using an average ironsand particle size of 65 µm. The compressive strength of these pellets after sintering at 1200 °C in air for 2 hr was measured to be 976 N, meeting the expected feedstock requirements for a shaft reactor. This strength was attributed to interparticle bonding arising from extensive recrystallisation of titanohematite grains from oxidation of TTM, as well as the formation of a liquid bonding phase due to melting and diffusion of the binders. Building on these results, alternative binders were then explored in order to lower the required sintering temperature. A combination of both organic and inorganic binders was found to deliver optimum performance, wherein carboxymethyl-cellulose based binders provided strength in the green pellets, whilst inorganic binders, such as calcium borate or ground glass, promoted high sintered strengths. 相似文献
67.
《Ceramics International》2022,48(12):16808-16812
Flash sintering has been reported in various ceramics. Nevertheless, anion and cation conductors exhibit different flash-sintering behaviors, and the interaction mechanism between the conductive species and the sintering environment has remained unclear. Herein, we report the flash-sintering phenomena of a typical cation conductor, Na3Zr2(SiO4)2(PO4) with anode region surrounded by air and NaNO3 environments. The results prove that the ionic behavior and joule heating distribution can be controlled by changing the electrode environment. Four possible scenarios describing the ion migration behavior and interaction with the environment are proposed for providing a guidance for controlling the ion interaction behavior during flash sintering. 相似文献
68.
《Ceramics International》2022,48(14):19618-19625
A series of Bi0.97?xNa0.03MgxCuSeO (0 ≤ x ≤ 0.12) was fabricated by a two?step solid?state reaction and spark plasma sintering (SPS), and the influence of Mg2+ doping on the thermoelectric properties of Bi0.97Na0.03CuSeO was systematically investigated. The SPS processed?Bi0.97?xNa0.03MgxCuSeO had a ZrSiCuAs?type tetragonal crystal structure (space group P4/nmm). The Mg2+ doping appreciably enhanced the electrical conductivity due to the increase in hole concentration. Furthermore, the Mg2+ doping increased the grain boundary areas and bulk porosity and induced the strain field and mass fluctuations, thereby reducing the phonon thermal conductivity. We significantly improved the thermoelectric performance of Bi0.97?xNa0.03MgxCuSeO (0 ≤ x ≤ 0.12) by enhancing the thermoelectric power factor and by reducing the thermal conductivity. 相似文献
69.
文中将大冶群角砾岩根据成因分为六种类型,总结出六种类型角砾岩野外区分际志便于野外人员掌握。据各类型角砾岩的成因及特征,总结了含铅锌矿角砾岩是由同沉积断裂角砾岩、滑塌角砾岩和构造—岩溶角砾岩组成的复成因角砾岩。进而归纳其野外鉴别特征及分布控制条件。掌握了含铅锌矿角砾岩分布规律在鄂东地区大冶群里寻找铅锌矿就会有新的进展。 相似文献
70.